Episode Details
Back to Episodes
Lecture 11: Allocation in Hybrid Power Production; Chemical Potentials and Partial Pressures
Description
MIT 2.43 Advanced Thermodynamics, Spring 2024
Instructor: Gian Paolo Beretta
View the complete course: https://ocw.mit.edu/courses/2-43-advanced-thermodynamics-spring-2024/
Complete course table of contents with hyperlinks to slides and video timestamps: https://ocw.mit.edu/courses/2-43-advanced-thermodynamics-spring-2024/resources/mit2_43_s24_toc_slides_pdf/
Complete course analytical index with hyperlinks to slides and video timestamps: https://ocw.mit.edu/courses/2-43-advanced-thermodynamics-spring-2024/resources/mit2_43_s24_index_slides_pdf/
YouTube Playlist: https://www.youtube.com/playlist?list=PLUl4u3cNGP6309d0oJDiVo1CvxUQXJ2il
This lecture covers: More on exergies: cogeneration, trigeneration. More on allocation. Introduction to multicomponent systems. Role of chemical potentials and intermolecular forces. Partial pressures. Partial properties. Duhem-Margules relation. Few vs many particle systems.
Instructor suggests to set viewing speed at 1.5 for faster learning.
Slides for this lecture: https://ocw.mit.edu/courses/2-43-advanced-thermodynamics-spring-2024/resources/mit2_43_s24_lec11_pdf/
Key moments:
00:00:00 - Introduction
00:00:31 - Review: Exergy in Heating and Cooling Bulk Flows
00:04:36 - Review: Minimum Exergy for Low Temperature Heating
00:07:30 - Review: Flame-Based Fuel-to-Power Conversion
00:08:59 - Review: Inherent Irreversibility of Flames
00:09:52 - Efficient and Inefficient Uses of Fossil Fuels
00:33:01 - Review: Allocation Problem in Cogeneration (CHP)
00:41:59 - Review: Allocation Problem in Hybrid Facilities
00:53:48 - Introduction to Part II: Chemical Potentials etc
00:55:09 - Stable-Equilibrium Properties of Mixtures
00:57:08 - Small Systems: Specific Properties Depend on “n”
01:00:43 - Large “n” Limit: Simple-System Approximation
01:12:15 - Partial Pressures to Measure Chemical Potentials
01:18:59 - Partial Properties from the Chemical Potentials
01:27:42 - Mixture Properties from the Partial Properties
License: Creative Commons BY-NC-SA
More information at https://ocw.mit.edu/terms
More courses at https://ocw.mit.edu
Support OCW at http://ow.ly/a1If50zVRlQ
We encourage constructive comments and discussion on OCW’s YouTube and other social media channels. Personal attacks, hate speech, trolling, and inappropriate comments are not allowed and may be removed. More details at https://ocw.mit.edu/comments.
Learn more about your ad choices. Visit megaphone.fm/adchoices